Tricarbonyl[η5-2-(methyldiphenylphosphaniumyl)-1,3,4-triphenylcyclopentadienyl]molybdenum(0)
نویسندگان
چکیده
The title compound, [Mo(C(36)H(29)P)(CO)(3)], contains an Mo(0) atom with a typical piano-stool coordination defined by the phospho-nium cyclo-penta-dienylide ligand η(5)-1-(methyl-diphenyl-phosphanium-yl)-2,3,5-triphenyl-2,4-cyclo-penta-dien-1-yl and by three carbonyl groups. The distance between the Mo(0) atom and the cyclo-penta-dienyl ring is 2.0616 (13) Å.
منابع مشابه
Crystal structures of trans-acetyldicarbonyl(η5-cyclopentadienyl)(dimethylphenylphosphane)molybdenum(II) and trans-acetyldicarbonyl(η5-cyclopentadienyl)(ethyldiphenylphosphane)molybdenum(II)
The title compounds, [Mo(C5H5)(COCH3)P(CH3)2(C6H5)(CO)2], (1), and [Mo(C5H5)(COCH3)P(C2H5)(C6H5)2)(CO)2], (2), have been prepared by phosphine-induced migratory insertion from [Mo(C5H5)(CO)3(CH3)]. Both complex mol-ecules exhibit a four-legged piano-stool geometry with trans-disposed carbonyl ligands along with Mo-P bond lengths and C-Mo-P angles that reflect the relative steric pressure of the...
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